This title provides detailed coverage of classic inorganic reaction mechanisms and organometallic reaction mechanisms. The coverage of the mechanisms expected for reactions of transitions metal complex includes the kinetic studies used to differentiate possible mechanisms. This combination of coordination complexes and organometallic complexes is unique to this title.
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Describing how transition metal complexes react and the type of data used to determine how complexes react, this work provides excellent introductions, extensive problems, and thought-provoking summaries in every chapter. Complete with excellent references, this second edition has been updated with new problems and increased information on NMR techniques, dissociative reactions of square-planar complexes, seventeen-electron complexes, organometallic transfer, and oxidative-addition and reductive-elimination reactions.
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Overview This textbook is for a one-semester course in kinetics and mechanisms of inorganic reactions. In this edition, references have been updated and new problems have been added to each chapter. Information on NMR techniques and other newer techniques, such as time-resolved infrared spectroscopy, have been added to the chapter on chemical kinetics.
The chapter describing ligand substitution reactions on square planar complexes now includes a section on dissociative reactions of square-planar complexes. Significant new material on reactions of seventeen electron complexes is included in the coverage of organometallic substitution reactions, while the material on oxidative-addition and reductive-elimination reactions has been extensively rewritten.
Inorganic and Organometallic Reaction Mechanisms / Edition 2
The chapter on inorganic electron transfer through inner and outer sphere mechanisms has been augmented by a substantial section on organometallic electron transfer. About the Author Jim D.
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